Solvents. 2-Butoxyethanol is an organic compound with the chemical formula BuOC 2 H 4 OH (Bu = CH 3 CH 2 CH 2 CH 2).This colorless liquid has a sweet, ether-like odor, as it derives from the family of glycol ethers, and is a butyl ether of ethylene glycol.As a relatively nonvolatile, inexpensive solvent, it is used in many domestic and industrial products because of its properties as a surfactant. Instability 0: Normally stable, even under fire conditions. 2-Butoxyethanol is a clear colorless liquid that smells like ether. ETHYLENE GLYCOL DIBUTYL ETHER may react violently with strong oxidizing agents. On November 21, 2003 (68FR65648), the EPA proposed to remove the compound ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) (Chemical Abstract Service (CAS) No. [1] Sie reagiert mit Luftsauerstoff langsam zu Peroxiden. Ethylene glycol and propylene glycol are organic compounds. as part of that chemical's infrastructure.                R = alkyl or aryl groups Ethylene glycol is odorless; odor does not provide any warning of … Data from animal studies have been examined from the standpoint of dose-response relationships and the sensitivity of various animal species, including man, to the effects of this chemical. 111-76-2) from the HAP list in CAA section 112(b)(1), 42 U.S.C. Several studies of rodents exposed orally or by inhalation showed ethylene glycol to be fetotoxic. When aerosolized it acts as a disinfectant. Diethylene glycol butyl ether (2-(2-Butoxyethoxy)ethanol) ... is produced by the reaction of ethylene oxide and n-butanol with an alkalic catalyst. 2 BUTOXYETHANOL BUTYL GLYCOL ETHYLENE GLYCOL BUTYL ETHER Technical grade 2-Butoxyethanol is an organic solvent which is a clear, colourless liquid with an ether-like odour.                R = alkyl C7 or less; or R = phenyl or alkyl substituted phenyl; On August 29, 1997, the ACC's Glycol Ethers Panel submitted a petition to delete EGBE (CAS No. On November 18, 2004, the Environmental Protection Agency (EPA) removed ethylene glycol monobutyl ether (EGBE) from the Clean Air Act (CAA) list of Hazardous Air Pollutants (HAP). [1] Die Verbindung hat eine geringe akute Toxizität. Formula. List of Hazardous Air Pollutants, Petition Process, Lesser Quantity Designations, Source Category List; Petition To Delist of Ethylene Glycol Monobutyl Ether . 112-34-5. Diethylene glycol monobutyl ether for synthesis Synonym: Butyl carbitol, 2-(2-Butoxyethoxy) ethanol, Butyl diglycol, Diethylene glycol monobutyl ether CAS Number 112-34-5. 13/606, Safepharm Laboratories, Ltd., Derby, U.K. Report to Mitsubishi Petrochemical Co., Ltd., Tokyo, Japan. NOTE: For all listings above which contain the word "compounds" and for glycol ethers, the following applies: Unless otherwise specified, these listings are defined as including any unique chemical substance that contains the named chemical (i.e., antimony, arsenic, etc.) Rats and mice chronically (long-term) exposed to ethylene glycol in their diet exhibited signs of kidney toxicity and liver effects. Which products contain ethylene glycol? In both the ethylene and diethylene glycol series, the relative rate of absorption declined from methyl to ethyl to butyl ether derivatives. Triethylene glycol, TEG, or triglycol is a colorless odorless viscous liquid with molecular formula HOCH 2 CH 2 OCH 2 CH 2 OCH 2 CH 2 OH. Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE is incompatible with the following: Oxidizers (NIOSH, 2016). Alcohols exhibit both … It and its toxic byproducts first affect the central nervous system (CNS), then the heart, and finally the kidneys. Diethylene glycol monobutyl ether. [8], Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium. This document examines the occupational health risks associated with exposure to ethylene glycol monobutyl ether (EGBE) and its acetate, ethylene glycol monobutyl ether acetate (EGBEA). Ethylene glycol (EG) is a colorless, odorless, bittersweet-tasting liquid that has many household and commercial uses. C10-H22-O4. 111-76-2. Glycol ethers are a group of solvents based on alkyl ethers of ethylene glycol or propylene glycol commonly used in paints and cleaners. Following the receipt of the petition, we conducted a preliminary evaluation to determine whether the petition was complete according to Ag… AGENCY: Environmental Protection Agency (EPA). 2-BE itself is not commercially produced in Canada. Linear Formula HOCH 2 CH 2 OCH 2 CH 2 O(CH 2) 3 CH 3. Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of hazardous air pollutants (glycol ethers category) in November 2004 - Federal Register - November 29, 2004 (69 FR 69320). 2. , except CAS #111-76-2, ethylene glycol mono-butyl ether, also known as EGBE or 2- Butoxyethanol. Hazardous Agents; Triethylene glycol monobutyl ether; Triethylene glycol monobutyl ether . Ein 10%iger Wasserzusatz unterdrückt die Aluminiumkorrosion und beschleunigt die Magnesiumkorrosion. 111-76-2) In Support of Summary Information on the Integrated Risk Information System (IRIS). On November 29, 2004 (69FR69320) this proposal was made final. 7412(b)(1). Formula. This original list included 189 pollutants. Am Siedepunkt ist jedoch eine langsame oberflächliche Korrosion zu beobachten. [8] Glycolmonoalkylether verhalten sich inert gegenüber Leichtmetallen wie Aluminium oder Magnesium. The level of exposure depends upon the dose, duration, and work being done. Ingestion of sufficient amounts can be fatal. [9] Contact Us to ask a question, provide feedback, or report a problem. TEGBE. Ethylene Glycol Ethers Group - information sheet - Canada.ca Hazardous Agents; By Types Of Agents; Solvents ; Glycol Ethers (E Series) Diethylene glycol monobutyl ether; Diethylene glycol monobutyl ether. Thus, EGBE is no longer subject to the Maximum Achievable Control Technology (MACT), residual risk and other specific requirements found in the CAA. Mention of ethylene glycol monobutyl ether is also in order because of its extensive use in industry.                R' = R, H, or groups which, when removed, yield glycol ethers with the structure: R-(OCH2CH)n-OH. Learn more. It is used as a plasticizer for vinyl polymers.It is also used in air sanitizer products, such as "Oust" or "Clean and Pure". Criteria are also provided for eliminating or minimizing the risks encountered by workers during the manufacture and use of EGBE and EGBEA. Polymers are excluded from the glycol category. low . Ein 10%iger Wasserzusatz unterdrückt die Aluminiumkorrosion und beschleunigt die Magnesiumkorrosion. 2-butoxyethanol may also be listed as ethylene glycol monobutyl ether, ethylene glycol butyl ether, Butyl Cellosolve, ethylene glycol n-butyl ether, butyl Oxitol, Dowanol EB, glycol butyl ether, Polysolv, and Ektasolve EB. Ashby, J; Tennant, RW. Ethylene Glycol: Ethylene glycol is used as raw material for the production of polyester fibers and as an automotive antifreeze. 2-Butyloxyethanol also caused loss of sterols from … Ethylene glycol monobutyl ether (EB) Diethylene glycol monobutyl ether (DEB) Triethylene glycol monobuthyl ether (TEB) Multi-ethylene glycol monobutyl ether(PEB) CAS. 2-BE is widely used in a range of commercial and consumer products, such as paints, cleaning products and solvents, as well as in some industrial applications. : E179-4 CAS-No 111-76-2 Synonyms 2-Butoxyethanol; Butyl cellosolve; Butyl glycol Recommended Use Laboratory chemicals. Ethylene glycol (IUPAC name: ethane-1,2-diol) is an organic compound with the formula (CH 2 OH) 2. 143-22-6 / Molecular formula . These criteria include recommendations for preventing … U.S. Environmental Protection Agency. Production Industrial routes. Ecological information Propylene Glycol: Propylene Glycol is used as a solvent for intravenous, oral, and topical pharmaceutical preparations. Glycols are also used as liquid desiccants for natural gas and in air conditioning systems. Alternative Name. Diethylene glycol ethers were absorbed more slowly than the corresponding ethylene glycol ethers. CAS Number. Abbreviations for 2-butoxyethanol include EGBE and BE [1]. If halogenated, they should be collected in container B. Ethylene Glycol Monobutyl Ether (Laboratory) Revision Date 17-Jan-2018 Aspiration hazard No information available Symptoms / effects,both acute and delayed Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting Endocrine Disruptor InformationNo information available Other Adverse Effects No information available. To implement this action, EPA revised footnote 2 of the list (42 U.S.C. Ethylene glycol is a “toxic alcohol”, meaning that although chemically it is similar to ethanol (the active component of alcoholic beverages), it is much more poisonous if consumed. Ethanol and fomepizole may be effective. It is an odorless, colorless, sweet-tasting, viscous liquid. 2010. United States Environmental Protection Agency, removed from the list of hazardous air pollutants in December 2005, removed from the list of hazardous air pollutants (glycol ethers category) in November 2004, removed from the list of hazardous air pollutants in June 1996, removed from the list of hazardous air pollutants in August 2000, Benzene (including benzene from gasoline), Cresols/Cresylic acid (isomers and mixture), Dichloroethyl ether (Bis(2-chloroethyl)ether), Epichlorohydrin (l-Chloro-2,3-epoxypropane), Ethylidene dichloride (1,1-Dichloroethane), Methyl chloroform (1,1,1-Trichloroethane), Propylene dichloride (1,2-Dichloropropane), Vinylidene chloride (1,1-Dichloroethylene), Arsenic Compounds (inorganic including arsine). Ethylene glycol monobutyl ether (EGBE) (2-Butoxyethanol) - removed from the list of … The ether being relatively unreactive. 1 - X'CN where X = H' or any other group where a formal dissociation may occur. 2. The available information on the acute and subchronic toxicity of ethylene glycol monobutyl ether is reviewed. DEG is used as a component of multiple different products including antifreeze preparations, cosmetics, lubricants, brake fluids, wallpaper strippers, heating/cooling fuel and as a plasticizer. Where is it found and how is it used? 111-76-2 - POAOYUHQDCAZBD-UHFFFAOYSA-N - Ethylene glycol mono-n-butyl ether - Similar structures search, synonyms, formulas, resource links, and other chemical information. The acute and subehronic toxicity of EGEE, EGPE and EGBE was reviewed by C. C. Conaway (Texaco, 111-76-2) from the group of glycol ethers" as described in the Federal Register FRL-7841-8. Impurities. 2-Butoxyethanol acetate Butyl Cellosolve acetate Butyl glycol acetate EGBEA Ektasolve EB acetate Ethylene glycol butyl ether acetate It can harm the eyes, skin, kidneys, and blood. Synonyms. Colorless liquid with a mild odor. (1991) Definitive relationships among chemical structure, carcinogenicity and mutagenicity for 301 chemicals tested by the U.S. NTP. In rats, deaths in response to single oral exposures are attributable to narcosis, whereas delayed deaths result from lung congestion and renal failure. ethylene glycol monobutyl ether 203-905-0 111-76-2 Retain Acute Tox. In postnatal studies, there were no significant effects on pup growth or survival at maternally toxic dose levels. EPA/635/R-08/006F. Ethylene glycol is odorless; odor does not provide any warning of inhalation exposure to hazardous concentrations. It attacks some forms of plastics, rubber and … DIETHYLENE GLYCOL MONOBUTYL ETHER is a ether-alcohol derivative. Thus, EGBE is no longer subject to the Maximum Achievable Control Technology (MACT), residual risk and other specific requirements found in the CAA. Es ist in der Regel in Konzentrationen von weniger als 2 % in den Haarfärbemitteln enthalten. 12. Diese Seite wurde zuletzt am 2. 2-Butoxyethanol is used in many industries. Molecular Weight 162.23 . They react with oxoacids and carboxylic acids to form esters plus water. Alternative Name. Surfactant alcohol ethoxylates and their derivatives - removed from the list of hazardous air pollutants in August 2000 - Federal Register – August 2, 2000 (65 FR 47342). Beim Menschen wurde nach oraler Exposition mit etwa 0,5 und 1,5 g/kg Körpergewicht und anfänglich schweren Symptomen eine vollständige Erholung beobachtet.[7]. Diamond Hazard Value Description; 1 1 0 Health 1: Can cause significant irritation. Am Siedepunkt ist jedoch eine langsame oberflächliche Korrosion zu beobachten. Oxidizing agents convert alcohols to aldehydes or ketones. A U.S. Environmental Protection Agency review finds 2-butoxyethanol is not toxic to reproduction or development. May generate flammable and/or toxic gases with alkali metals, nitrides, and other strong reducing agents. ... WGK 1 slightly hazardous to water: Disposal: 3 Relatively unreactive organic reagents should be collected in container A. Methyl Ethyl Ketone – removed from the list of hazardous air pollutants in December 2005 - Federal Register - December 19, 2005 (70 FR 75047). Caprolactam – removed from the list of hazardous air pollutants in June 1996 - Federal Register - June 18, 1996 (61 FR 30816).                R' = H or alkyl C7 or less; or OR’ consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or sulfonate. Appearance. C 4 H 9 OCH 2 CH 2 OCH 2 CH 2 OH. The ether being relatively unreactive. The EU Ecolabel may not be awarded to substances or mixtures classified as such. It is completely miscible with water and most organic solvents making it very versatile as an ingredient in cleaners, degreasers, paints, varnishes etc. In a biphasic kerosene-water system, 3-methoxybutanol, 2-butyloxyethanol, and diethylene glycol monobutyl ether were again found to be more toxic than ethylene glycol monomethyl ether. DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE; NFPA 704. MDL number MFCD00002881. [1] In kommerziellen Produkten werden 0,008 – 0,012 % Butylhydroxytoluol zugefügt um die Bildung von Peroxiden zu unterdrücken. They react with oxoacids and carboxylic acids to form esters plus water. tration. Conclusion. Ethylene glycol is chemically broken down in the body into toxic compounds. Footnote 14 111-76-2) from the group of glycol ethers. Inhalation exposure to air and light only at exposure levels that harm the pregnant animal, sweet-tasting, liquid! Reproductive Hazard this material ( or a component ) has been shown to cause to... 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